Structural relaxations of an electrorheological fluid (ERF) due to cha
nges in the applied electrical field strength or shear rate are observ
ed on time scales 1 s < t < 40 000 s. Commercial ERFs consisting of me
soscopic polyurethane particles in a silicone oil matrix were studied
by three different experimental techniques in order to obtain and comp
are the characteristic relaxation times. It is demonstrated that diele
ctric spectroscopy, viscosimetry and light transmission experiments re
present the same results concerning the structural relaxation phenomen
a of ERFs when electrical fields are applied. The tendency of strong i
nduced dipoles to align the particles in the direction of the field in
creases the effective dipole moment and therefore Delta epsilon, the s
hear viscosity eta and the amount of light transmitted along the field
direction in an ITO/glass sandwich cell. The optical experiment is ca
pable of resolving fast processes within the first 1 ms if large elect
rical fields are applied. The effects of electrophoresis and shearing,
which both counteract the field induced structures, are also addresse
d.