F. Aladel et Sma. Durrani, SINGLEPHOTON AND MULTIPHOTON ABSORPTION OF CARBON-DIOXIDE LASER LINESBY SO2 AND CO2 MOLECULES, Nuovo cimento della Societa italiana di fisica. D, Condensed matter,atomic, molecular and chemical physics, biophysics, 17(10), 1995, pp. 1113-1120
We have used 60 rovibrational lines of a Lumonics TEA CO2 laser to rec
ord the spectra of coincidence of SO2 IR absorption with CO2 laser emi
ssion. We extended the same type of investigation to CO2 molecules and
observed an absorption at practically all the rovibrational lines of
the laser. We have also recorded the increase of absorption with press
ure of the studied molecule and with its temperature. Our work reveals
very accurately the fine structure of these absorptions that shows a
clear discreteness in the intensities of the lines. Some implication o
f this discreteness in multiphoton absorption is also presented, throu
gh data that indicate very strong vibrational coupling between ground
and excited electronic states of SO2.