SULFURIC ACID-CATALYZED ACETOLYSIS OF ANOMERIC ETHYL 2,3,4,6-TETRA-O-ACETYL-D-GLUCOPYRANOSIDES - KINETICS AND MECHANISM

Authors
KACZMAREK J PREYSS M LONNBERG H SZAFRANEK J
Citation
J. Kaczmarek et al., SULFURIC ACID-CATALYZED ACETOLYSIS OF ANOMERIC ETHYL 2,3,4,6-TETRA-O-ACETYL-D-GLUCOPYRANOSIDES - KINETICS AND MECHANISM, Carbohydrate research, 279, 1995, pp. 107-116
Citations number
30
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Carbohydrate research → ACNP
ISSN journal
00086215
Volume
279
Year of publication
1995
Pages
107 - 116
Database
ISI
SICI code
0008-6215(1995)279:<107:SAAOAE>2.0.ZU;2-F
Abstract
Kinetics of the acetolysis and concomitant anomerization of ethyl 2,3, 4,6-tetra-O-acetyl-alpha- and -beta-D-glucopyranosides in a mixture of acetic anhydride, acetic acid, and sulfuric acid have been studied. T he progress of the reactions was followed by gas chromatography, and t he rate constants of the partial reactions were calculated on the basi s of the time-dependent product distributions obtained. The mechanisms of the reactions are discussed.