EFFECT OF CLAY POLYMER INTERACTIONS ON SHALE STABILIZATION DURING DRILLING

Citation
L. Bailey et al., EFFECT OF CLAY POLYMER INTERACTIONS ON SHALE STABILIZATION DURING DRILLING, Langmuir, 10(5), 1994, pp. 1544-1549
Citations number
21
Categorie Soggetti
Chemistry Physical
Journal title
ISSN journal
07437463
Volume
10
Issue
5
Year of publication
1994
Pages
1544 - 1549
Database
ISI
SICI code
0743-7463(1994)10:5<1544:EOCPIO>2.0.ZU;2-V
Abstract
Adsorption measurements were used to investigate the mechanisms of sha le stabilization by water-soluble polymers, which are commonly added t o drilling fluids to control reactive shale formations. High molecular weight (10(7)) polyacrylamides of varying ionicity were adsorbed on w ell-characterized K-smectite, from solutions of varying electrolyte co ncentration. Polymer adsorption was found to be strongly dependent on the ionicity of the polymer and on the ionic strength of the medium, d ue to charge screening effects and the salt-dependent energy of tactoi d assembly. The interaction of these polymers with a standard shale ro ck was investigated by conventional oilfield cuttings rolling tests an d in an apparatus designed to simulate wellbore conditions of pressure and flow rates. The results show that under conditions promoting adso rption of polymers, disintegration and dispersion are inhibited, altho ugh the near wellbore material still imbibes water and ions. The stabi lity of the wellbore is also dependent on the nature of the polymer-cl ay interaction; the strongly bound cationic polymer is able to limit c lay swelling.