Adsorption measurements were used to investigate the mechanisms of sha
le stabilization by water-soluble polymers, which are commonly added t
o drilling fluids to control reactive shale formations. High molecular
weight (10(7)) polyacrylamides of varying ionicity were adsorbed on w
ell-characterized K-smectite, from solutions of varying electrolyte co
ncentration. Polymer adsorption was found to be strongly dependent on
the ionicity of the polymer and on the ionic strength of the medium, d
ue to charge screening effects and the salt-dependent energy of tactoi
d assembly. The interaction of these polymers with a standard shale ro
ck was investigated by conventional oilfield cuttings rolling tests an
d in an apparatus designed to simulate wellbore conditions of pressure
and flow rates. The results show that under conditions promoting adso
rption of polymers, disintegration and dispersion are inhibited, altho
ugh the near wellbore material still imbibes water and ions. The stabi
lity of the wellbore is also dependent on the nature of the polymer-cl
ay interaction; the strongly bound cationic polymer is able to limit c
lay swelling.