We measured the index of refraction n(lambda) of Zn-doped LiNbO3 grown
from a congruent melt as a function of the Zn concentration in the cr
ystal. The Zn concentration c(Zn) in a sample was determined by electr
on microprobe technique. The refractive index n(lambda, c(Zn)) is desc
ribed by a generalized Sellmeier equation for 400 < lambda < 1200 nm a
nd c(Zn) up to 8 mol% ZnO. Calculated phase-matching conditions of non
linear effects like second-harmonic generation are in excellent agreem
ent with experimental results obtained with the same set of crystals.