RELATIVE REACTIVITIES IN VINYL COPOLYMERIZATION

Authors
ALFREY T PRICE CC
Citation
T. Alfrey et Cc. Price, RELATIVE REACTIVITIES IN VINYL COPOLYMERIZATION, Journal of polymer science. Part A, Polymer chemistry, 34(2), 1996, pp. 157-162
Citations number
NO
Categorie Soggetti
Polymer Sciences
Journal title
Journal of polymer science. Part A, Polymer chemistry → ACNP
ISSN journal
0887624X
Volume
34
Issue
2
Year of publication
1996
Pages
157 - 162
Database
ISI
SICI code
0887-624X(1996)34:2<157:RRIVC>2.0.ZU;2-R
Abstract
From data in tire literature on relative rates of copolymerization it has been possible to evaluate two constants, Q and e, characteristic o f an individual monomer, which appear to account satisfactorily for it s behavior in copolymerization, The constant Q describes the ''general monomer reactivity'' and is apparently related to possibilities for s tabilization in a radical adduct. The constant e labs account of polar factors influencing copolymerization.