CLEAVABLE EPOXY-RESINS - DESIGN FOR DISASSEMBLY OF A THERMOSET

Citation
Sl. Buchwalter et Ll. Kosbar, CLEAVABLE EPOXY-RESINS - DESIGN FOR DISASSEMBLY OF A THERMOSET, Journal of polymer science. Part A, Polymer chemistry, 34(2), 1996, pp. 249-260
Citations number
20
Categorie Soggetti
Polymer Sciences
ISSN journal
0887624X
Volume
34
Issue
2
Year of publication
1996
Pages
249 - 260
Database
ISI
SICI code
0887-624X(1996)34:2<249:CE-DFD>2.0.ZU;2-4
Abstract
A series of cycloaliphatic diepoxides with cleavable acetal links were synthesized and characterized. These materials were shown to undergo thermosetting reactions with cyclic anhydride in very similar fashion to a commercial cycloaliphatic epoxide, but cured samples were easily dissolved in a variety of acid-containing solvent mixtures. Such mater ials can extend the utility of thermosetting epoxies by preserving the ir positive attributes while eliminating their well known intractabili ty after curing. The latter property is particularly a problem for man ufacturers designing products for disassembly at end of use in order t o facilitate recycling. (C) 1996 John Wiley & Sons, Inc.