BINDING OF THIOETHER SULFUR TO TRIVALENT CHROMIUM - A FAMILY OF CRS2N2O2 COMPLEXES DERIVED FROM ACYCLIC LIGANDS

Authors
PATTANAYAK S DAS DK CHAKRABORTY P CHAKRAVORTY A
Citation
S. Pattanayak et al., BINDING OF THIOETHER SULFUR TO TRIVALENT CHROMIUM - A FAMILY OF CRS2N2O2 COMPLEXES DERIVED FROM ACYCLIC LIGANDS, Inorganic chemistry, 34(26), 1995, pp. 6556
Citations number
39
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
34
Issue
26
Year of publication
1995
Database
ISI
SICI code
0020-1669(1995)34:26<6556:BOTSTT>2.0.ZU;2-S
Abstract
The title complexes are of type [Cr(RxL)]ClO4 obtained from dithiaalky l-substituted triazene 1-oxides [RN(O)NNHC6H4S](2)(CH2)(x) (H(2)RxL; R = Me, Ph; x = 2, 3), chromium(III) chloride tetrahydrate, and sodium perchlorate. We have here the first structurally characterized chromiu m(III)-thioether binding by an acyclic ligand.