SOLVENT-INDUCED SENSITIZATION OF ION TRACKS IN PET ANALYZED BY SMALL-ANGLE X-RAY-SCATTERING AND DIFFERENTIAL SCANNING CALORIMETRY

Citation
T. Steckenreiter et al., SOLVENT-INDUCED SENSITIZATION OF ION TRACKS IN PET ANALYZED BY SMALL-ANGLE X-RAY-SCATTERING AND DIFFERENTIAL SCANNING CALORIMETRY, Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms, 105(1-4), 1995, pp. 200-203
Citations number
14
Categorie Soggetti
Physics, Nuclear","Nuclear Sciences & Tecnology","Instument & Instrumentation
ISSN journal
0168583X
Volume
105
Issue
1-4
Year of publication
1995
Pages
200 - 203
Database
ISI
SICI code
0168-583X(1995)105:1-4<200:SSOITI>2.0.ZU;2-Q
Abstract
The influence of the organic solvent N,N,-dimethylformamide (DMF) on i on tracks in polyethyleneterephthalate (PET) was investigated by small -angle X-ray scattering (SAXS) and by differential scanning calorimetr y (DSC). The experiments were performed on non-irradiated, irradiated and DMF-treated samples. After ion irradiation the SAXS pattern change d considerably. From the comparison of the SAXS pattern of the irradia ted samples before and after DMF sensitization, it can be concluded th at DMF induces a process restoring the lamellar structure. With DSC we determined the melting enthalpy. Compared with non-irradiated PET the melting enthalpy of irradiated samples decrease. By DMF-sensitization this decrease of melting enthalpy is enhanced.