In this article we apply an analytical solution of the radiosity equat
ion to compute vegetation indices, reflectance spectra, and the spectr
al bidirectional reflectance distribution function for simple canopy g
eometries. We show that nonlinear spectral mixing occurs due to multip
le reflection and transmission from surfaces. We compare radiosity-der
ived spectra with single scattering or linear mixing models. We also d
evelop a simple model to predict the reflectance spectrum of binary an
d ternary mineral mixtures of faceted surfaces. The two-facet model is
validated by measurements of the reflectance.