Wd. Li et al., THE EFFECT OF THE POLISHING PAD TREATMENTS ON THE CHEMICAL-MECHANICALPOLISHING OF SIO2-FILMS, Thin solid films, 270(1-2), 1995, pp. 601-606
Polishing pads play an important role in chemical-mechanical polishing
(CMP) which has recently been recognized as the most effective method
to achieve global planarization in very large scale integrated circui
t multi-level interconnects. In this work, we have investigated CMP pe
rformances of SiO2 as a function of the time of soaking the pad in wat
er, pad conditioning, and pad surface temperature. It has been observe
d that the dynamic shear modulus G' of an IC1000 pad decreases to two
thirds of its dry value during 5 h water soaking, while its oxide remo
val rate remains practically unchanged. The shear modulus of a polishi
ng pad also decreases with the increase of pad temperature. For exampl
e, G' of an IC1000 pad drops approximately by a factor of 2 when tempe
rature increases from 40 degrees C to 80 degrees C. Correspondingly, i
ncreases of both oxide removal rate and planarization efficiency, whic
h is the step-height reduction per unit oxide removed on the ''up feat
ure'', have been observed when the slurry temperature increases (which
raises the pad surface temperature). Pad conditioning is a crucial st
ep in CMP. The oxide removal rate decreases with time during a CMP pro
cess without pad conditioning until reaching a low steady-state value.
On the other hand, the planarization efficiency increases with time d
uring a CMP process without pad conditioning. Possible mechanisms whic
h may lead to these observations are discussed.