Th. Ko et al., THE EFFECT OF PYROLYSIS ON THE PROPERTIES OF STABILIZED PAN FABRIC REINFORCED PHENOLIC RESINS FOR 2D CARBON-CARBON COMPOSITES, Polymer composites, 16(6), 1995, pp. 522-528
Two-dimensional (2D) carbon/carbon composites were prepared with pheno
lformaldehyde resin and a commercial stabilized PAN fabric. The effect
of pyrolysis on the microstructure and flexural strength of the compo
sites during the carbonization process was studied. The interaction be
tween fabric and matrix inhibited the decomposition and the thermal fr
agmentation, leading to a higher carbon yield for the final compositio
n. Because of the formation of strong bonding in the fiber/matrix inte
rface, the composites made with stabilized PAN fabric showed catastrop
hic failure and low flexural strength below carbonization temperatures
of 600 degrees C. Above 600 degrees C, the flexural strength of the c
omposites increased with the increase in the carbonization temperature
s, even when the fracture behavior showed catastrophic failure.