The frequency ratio of narrowband millisecond spikes during 17 solar f
lares has been measured and analyzed. The observations have been made
in the frequency range 0.3-3 GHz with the ETH Zurich spectrometers. Th
e events have been selected from spectrograms for their harmonic struc
ture. Autocorrelation in frequency yields the following major results:
(i) The ratio of the harmonic spike groups is not integer, and theref
ore the term 'harmonic' is strictly speaking inappropriate. (ii) The r
atios are independent of frequency. (iii) The ratios range from 1.06 t
o 1.54 with a prominent peak at 1.39+/-0.01. The cross-correlation of
the time profile of harmonic groups peaks at zero lag, demonstrating a
tight relation between individual spikes in associated groups. The re
sults require an emission mechanism that can produce harmonic emission
at a ratio 5:7 or 1:1.4 and vary significantly from this value. In se
veral cases 3, and in one case 4 harmonic bands have been observed. Pr
eviously proposed interpretations of harmonic spike emission are discu
ssed in view of the new observations.