Ya. Pusep et al., ATOMIC-SCALE CHARACTERIZATION OF INTERFACES IN THE GAAS ALGAAS SUPERLATTICES/, Materials science & engineering. B, Solid-state materials for advanced technology, 35(1-3), 1995, pp. 180-183
We present a new interpretation of the Raman spectra of GaAs/AlAs ultr
athin-layer superlattices based on the microscopic analysis of the opt
ical vibrational modes. The difference between normal and inverted int
erfaces is responsible for the lack of the inversion symmetry of the l
ayers with respect to the central plane, therefore confined modes can
no longer be considered as even or odd ones. All the optical vibration
al modes, independently of their quantum index, are now active in Rama
n scattering.