SYNTHESIS AND REACTIVITY OF SILICON TRANS ITION-METAL COMPLEXES .35. METALLO SILANOLS AND METALLO SILOXANES .9. SYNTHESIS OF THE DIASTEREOMERICALLY PURE FERRIO SILANOL (RS,SR)-CP(OC)(PH(3)P)FE-SI(ME)(PH)(OH) AND STRUCTURE OF (RR,SS)-CP(OC)(PH(3)P)FE-SI(ME)(PH)CL

Authors
MALISCH W NEUMAYER M FEY O ADAM W SCHUHMANN R
Citation
W. Malisch et al., SYNTHESIS AND REACTIVITY OF SILICON TRANS ITION-METAL COMPLEXES .35. METALLO SILANOLS AND METALLO SILOXANES .9. SYNTHESIS OF THE DIASTEREOMERICALLY PURE FERRIO SILANOL (RS,SR)-CP(OC)(PH(3)P)FE-SI(ME)(PH)(OH) AND STRUCTURE OF (RR,SS)-CP(OC)(PH(3)P)FE-SI(ME)(PH)CL, Chemische Berichte, 128(12), 1995, pp. 1257-1260
Citations number
31
Categorie Soggetti
Chemistry
Journal title
Chemische Berichte → ACNP
ISSN journal
00092940
Volume
128
Issue
12
Year of publication
1995
Pages
1257 - 1260
Database
ISI
SICI code
0009-2940(1995)128:12<1257:SAROST>2.0.ZU;2-S
Abstract
Irradiation of the ferrio chlorosilane Cp(OC)(2)Fe-Si(Me)(Ph)Cl (1) in the presence of Ph(3)P leads to Cp(OC)(Ph(3)P)Fe-Si(Me)(Ph)Cl (2) whi ch is formed as a mixture of diastereomers separated by crystallizatio n. Pure (RR,SS)-2 is converted highly stereoselectively into (RR,SS)-C p(OC)(Ph(3)P)Fe-Si(Me)(Ph)H (3) with LiAlH4, and further with dimethyl dioxirane into (RS,SR)-Cp(OC)(Ph(3)P)Fe-Si(Me)(Ph)(OH) (4). This ferri o silanol diasteromer is alternatively obtained by Cl/OH exchange with KOH from 2. Diastereomerically pure (RR,SS)-2 characterized by a sing le-crystal structure analysis.