Br gamma and He I 2.058 mu m images of the Galactic center reveal that
most of the Br gamma emission is associated with interstellar gas but
that the He I is largely concentrated on individual, luminous stars t
hat therefore must be hot. High-resolution spectra of these stars, emp
hasizing He I 2.058 mu m through Br gamma 2.166 mu m, are compared wit
h spectra of 98 hot, luminous stars from the literature and new spectr
a of 43 luminous galactic emission-line stars including late nitrogen
sequence Wolf-Rayet, luminous blue variable (LBV), Oe, Of, and ON supe
rgiant stars. Combining our data with other observations from the lite
rature, the He I sources in the central parsec include approximately f
ive Ofpe/WN stars and one late-WC star. The inferred luminosity and de
tection of Mg II emission lines in the spectrum of IRS 16NE make it a
likely LBV candidate. However, we find six stars with line widths < 50
0 km s(-1) which defy easy classification, even from the extensive lib
rary of comparison spectra we have compiled. Considering the ultraviol
et constraints of Serabyn & Lacy and Shields & Ferland and the large n
umber of peculiar hot stars, either we see this stellar population at
a very distinctive moment in its evolution, or the conditions of forma
tion or the evolution of the stars must be significantly altered by th
e environment in the central parsec.