H. Muller et C. Opitz, THE PERIODIC SYSTEM OF METAL-CLUSTERS - A TOOL FOR DERIVING VARIOUS FORMS OF ]]CLUSTER-MATTER[[, Croatica chemica acta, 68(4), 1995, pp. 721-743
A simple modified jellium model permits calculation of all the magic n
umbers of large metal clusters M(N) up to N = 1432 in excellent agreem
ent with experimental data. This success justifies further conclusions
to be drawn from this model: (1) the calculated aufbau principle enab
les construction of a Periodic System of (alkali metal) Clusters (PSC)
; (II) this PSC, strictly speaking a Periodic System of ''giant atoms'
', is a powerful tool for predicting the reactivity of free electron-l
ike metal clusters; (III) the formation of cluster dimers is discussed
exemplarily in detail in excellent agreement with experimental and th
eoretical experience; (IV) various forms of cluster-matter are outline
d in relation to new materials; (V) a great deal of work has to be don
e to confirm a number of unconventional predictions: new experiments a
nd new calculations are highly desirable.