AN OCTAHEDRAL RHENIUM CLUSTER WITH (CN) LIGANDS - THE CRYSTAL-STRUCTURE OF KCS3RE6S8(CN)(6)

Authors
SLOUGUI A MIRONOV YV PERRIN A FEDOROV VE
Citation
A. Slougui et al., AN OCTAHEDRAL RHENIUM CLUSTER WITH (CN) LIGANDS - THE CRYSTAL-STRUCTURE OF KCS3RE6S8(CN)(6), Croatica chemica acta, 68(4), 1995, pp. 885-890
Citations number
10
Categorie Soggetti
Chemistry
Journal title
Croatica chemica acta → ACNP
ISSN journal
00111643
Volume
68
Issue
4
Year of publication
1995
Pages
885 - 890
Database
ISI
SICI code
0011-1643(1995)68:4<885:AORCW(>2.0.ZU;2-3
Abstract
The title compound has been prepared by anionic exchange from Re6Te15 The structure has been solved from the single crystal Xray diffraction data. The compound is built of standard M(6)L(8)L(6)' units where L a re chalcogens in inner position and L' are apical (CN) groups. The Kion is octahedrally surrounded by apical ligands belonging to six diff erent units, while the Cs+ ions lie in complex anionic site.