R. Forteza et al., CALCULATION AND REFINEMENT OF THERMODYNAMIC PARAMETERS FROM THERMOMETRIC TITRATIONS .2. THE NEUTRALIZATION ENTHALPIES OF PHENOLS IN HYDRO-ALCOHOLIC, Thermochimica acta, 268, 1995, pp. 105-120
Several monoprotic and polyprotic phenols were analysed by thermometri
c titration in a 50:50 v/v methanol/water medium. The performance of v
arious methods for the calculation and refinement of thermodynamic par
ameters from thermometric titration data in the determination of the n
eutralization enthalpies of several phenols in hydro-alcoholic media i
s compared in terms of precision and the influence of the medium on th
e titration errors.