For the sake of the hydrogen electrochemical permeation method, the po
ssibility to obtain a thin and reliable palladium coating on iron has
been studied. Experiments were carried out at room temperature with a
PdCl2 solution. Electrochemical kinetic measurements were done to find
out the potential range in which the only possible reaction is the pa
lladium reduction. A well adherent palladium coating, covering homogen
eously the whole iron surface and thinner than 0.1 mu m, has been obta
ined.