SYNTHESIS OF THE FIRST THORIUM-CONTAINING NITRIDE PEROVSKITE, TATHN3

Citation
Ne. Brese et Fj. Disalvo, SYNTHESIS OF THE FIRST THORIUM-CONTAINING NITRIDE PEROVSKITE, TATHN3, Journal of solid state chemistry, 120(2), 1995, pp. 378-380
Citations number
27
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Physical
ISSN journal
00224596
Volume
120
Issue
2
Year of publication
1995
Pages
378 - 380
Database
ISI
SICI code
0022-4596(1995)120:2<378:SOTFTN>2.0.ZU;2-Q
Abstract
TaThN3 can be prepared from a reaction of Ta2Th2O9 and Ca3N2 at 1100-1 500 degrees C or from a reaction of Ta3N5 and Th3N4 at 1400 degrees C. This black polycrystalline material crystallizes in the perovskite st ructure type with a = 4.020(6) Angstrom. (C) 1995 Academic Press, Inc.