The existence of localized states at perfect InSb-like interfaces in A
lSb/InAs superlattices is predicted from ab initio pseudopotential cal
culations. Localized states are predicted in both the valence and cond
uction bands, the former being identifiable with the interface states
proposed by Kroemer, Nguyen, and Brar [J. Vac. Sci. Technol. 10, 1769
(1990)]. The existence of these interface localized states is invoked
to explain the reported experimental dependence of the band gap upon i
nterface types in such superlattices.