Id. Ryabchikov et al., GLASS-BEARING XENOLITHS FROM CAPE-VERDE - EVIDENCE FOR A HOT RISING MANTLE JET, Mineralogy and petrology, 55(4), 1995, pp. 217-237
Peridotitic xenoliths from melanephelinites of Sal Island, Cape Verde
Archipelago, have a compositional range from moderately depleted Iherz
olites to refractory harzburgites. Most xenoliths have protogranular t
extures but porphyroclastic and mylonitic textures are not uncommon. S
mall amounts of glass are present in the intergranular space of these
rocks which possibly, at least in part, represent quenched silicate me
lt which invaded these rocks just before they were excavated. These gl
asses contain microphenocrysts of olivine, clinopyroxene, and spinel,
as well as small grains of sulphides and metallic Fe-Ni alloys. Metall
ic phases were most likely produced by the desulphurization of sulfide
s, which also resulted in very low oxygen fugacities (several logarith
mic units below QFM buffer) in the interstitial glasses and associated
microphenocrysts. This is reflected in the chemical composition of th
e newly formed spinels which are characterised by low amounts of ferri
c iron. In contrast, primary spinel-bearing mineral assemblages of the
peridotites were formed at much higher f(O2), which were similar to t
hose estimated for the host nephelinites which have high titanomagneti
te contents.