SOLID ANGLES .5. CHIRAL MOLECULES AND THE CASE OF FACE SELECTIVITY

Citation
Dp. White et al., SOLID ANGLES .5. CHIRAL MOLECULES AND THE CASE OF FACE SELECTIVITY, Journal of mathematical chemistry, 18(2-4), 1995, pp. 99-114
Citations number
14
Categorie Soggetti
Chemistry,Mathematics
ISSN journal
02599791
Volume
18
Issue
2-4
Year of publication
1995
Pages
99 - 114
Database
ISI
SICI code
0259-9791(1995)18:2-4<99:SA.CMA>2.0.ZU;2-O
Abstract
In this paper we present the analytical algorithm to calculate the sol id angle of a collection of spheres in a hemisphere and quadrant. The methodology is a reliable and useful measure of partial steric congest ion and can readily be applied to chiral and pro-chiral molecules. Thi s algorithm lays the foundation for the application of a steric measur e to the prediction of diastereomeric and enantiomeric excess.