A CONVENIENT SYNTHESIS OF THE SIDE-CHAIN OF STEROLS

Authors
SCHMITTBERGER T UGUEN D
Citation
T. Schmittberger et D. Uguen, A CONVENIENT SYNTHESIS OF THE SIDE-CHAIN OF STEROLS, Tetrahedron letters, 37(1), 1996, pp. 29-32
Citations number
28
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
1
Year of publication
1996
Pages
29 - 32
Database
ISI
SICI code
0040-4039(1996)37:1<29:ACSOTS>2.0.ZU;2-4
Abstract
Potassium t-butoxide-induced Ramberg-Backlund rearrangement of chloros ulfones formed from a cyclopregnane-20-thiomethanol derivative has bee n shown to give Delta(22)-unsaturated steroids with high trans stereos electivity.