A CONVENIENT APPROACH TO THE AMINOCYCLITOL FRAGMENT OF PANCRATISTATINFROM 7-OXANORBORNENES

Authors
ACENA JL ARJONA O IRADIER F PLUMET J
Citation
Jl. Acena et al., A CONVENIENT APPROACH TO THE AMINOCYCLITOL FRAGMENT OF PANCRATISTATINFROM 7-OXANORBORNENES, Tetrahedron letters, 37(1), 1996, pp. 105-106
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
1
Year of publication
1996
Pages
105 - 106
Database
ISI
SICI code
0040-4039(1996)37:1<105:ACATTA>2.0.ZU;2-A
Abstract
A totally stereoselective route to an analogue aminocyclitol fragment of the alkaloid pancratistatin has been achieved starting from a 7-oxa norbornenic disulfone. The key step was the alkylative cleavage of the oxygen bridge to produce a highly oxygenated cyclohexenyl sulfone.