AZATRIQUINANE, AZATRIQUINACENE, AND A REMARKABLE DIMERIZATION PRODUCT

Authors
MASCAL M HEXT NM SHISHKIN OV
Citation
M. Mascal et al., AZATRIQUINANE, AZATRIQUINACENE, AND A REMARKABLE DIMERIZATION PRODUCT, Tetrahedron letters, 37(1), 1996, pp. 131-134
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
1
Year of publication
1996
Pages
131 - 134
Database
ISI
SICI code
0040-4039(1996)37:1<131:AAAARD>2.0.ZU;2-O
Abstract
Azatriquinane, an amine with a rigid, hemispherical topology, is synth esized in six steps from pyrrole. It is shown to be more basic than qu inuclidine, and can be dimerized by N-oxidation and treatment with bas e to give novel, highly strained heptacycle. Oxidation with chlorine g ives an azatriquinacene, a theoretical precursor to diazadodecahedrane .