To supply Brazilian needs in the held of quality of radionuclide analy
ses in environmental samples, the Institute for Radioprotection and Do
simetry of the National Nuclear Energy Commission (IRD/CNEN) has begun
a national intercomparison program (PNI) to encourage the development
and optimization of analytical methodologies for radionuclide determi
nation in environmental samples. Since its initiation, the PNI has pro
moted eight intercomparison runs involving 221 studies in a total of 4
85 analyses. These studies consist of the determination of different r
adionuclides in many kinds of environmental simulated matrices, like w
ater, milk and filtered air. The total analytical performance reached
by the 16 participant laboratories was: 73.7% good results (within all
limits), 10.2% of results in the warning zone and 16.1% unacceptable
results (out of the control limits). As was expected, the analytical p
erformance of the laboratories had improved after their participation
in the intercomparison runs, which emphasizes the importance of this c
ooperative work.