R. Delfanti et al., PLUTONIUM CONCENTRATION IN SEDIMENT CORES COLLECTED IN THE MEDITERRANEAN-SEA, Science of the total environment, 173(1-6), 1995, pp. 187-193
As is well known, the determination of plutonium isotopes in the marin
e environment is of great importance to calculate the contamination du
e to the nuclear industry and to better understand sedimentation proce
sses. In the last 20 years sea sediment cores have been collected in d
ifferent areas of the Mediterranean Sea by four Italian research teams
. The sampling depth ranged from 50 to 2800 m and the core lengths wer
e 10-30 cm. The radioanalytical procedures were based on plutonium sep
aration by anion exchange resins or by extraction chromatography with
Microthene-TOPO; plutonium electroplating was performed before alpha-s
pectrometry. The final chemical yields were determined by spiking with
Pu-236 or Pu-242. In some cases Pu-238 could be detected. As far as t
he vertical profiles are concerned, no significant subsurface maxima r
esulted for the cores collected at greatest depth; on the contrary int
eresting peaks were found for cores collected at 50-100 m depth.