SYNTHESIS AND CHARACTERIZATION OF ALTERNATING POLYMER

Citation
Zm. Li et al., SYNTHESIS AND CHARACTERIZATION OF ALTERNATING POLYMER, Journal of macromolecular science. Pure and applied chemistry, A31, 1994, pp. 557-569
Citations number
9
Categorie Soggetti
Polymer Sciences
ISSN journal
10601325
Volume
A31
Year of publication
1994
Supplement
5
Pages
557 - 569
Database
ISI
SICI code
1060-1325(1994)A31:<557:SACOAP>2.0.ZU;2-X
Abstract
This paper examines the copolymerization of alpha-methylstyrene (alpha -MS) and ethyl acrylate(EA) with a complexed initiating system of AlEt 2Cl and benzoyl peroxide(BPO). Effects of monomer ratio, monomer conce ntration, initiator composition and polymerization conditions on conve rsion, molecular weight and copolymer composition were studied. The co polymer was characterized by elemental analysis, IR, H-1-NMR, and C-13 -NMR. Results show that it is an alternating copolymer.