Dc. Galant et D. Goorvitch, ACCURATE EVALUATION OF QUANTUM INTEGRALS, Journal of quantitative spectroscopy & radiative transfer, 55(1), 1996, pp. 47-52
Combining an appropriate finite difference method with Richardson's ex
trapolation results in a simple, highly accurate numerical method for
solving a Schrodinger's equation. Important results are that error est
imates are provided, and that one can extrapolate expectation values r
ather than the wavefunctions to obtain highly accurate expectation val
ues. We discuss the eigenvalues, the error growth in repeated Richards
on's extrapolation, and show that: the expectation values calculated o
n a crude mesh can be extrapolated to obtain expectation values of hig
h accuracy.