SYNTHESIS AND PROPERTIES OF AROMATIC TELECHELIC MONODISPERSE DIOLS .1. RADICAL-INITIATED ADDITION OF 10-UNDECEN-1-OL TO NEW AROMATIC ALPHA,OMEGA-DITHIOLS

Authors
AMEDURI B BOUTEVIN B KHAMLICHI M ROBIN JJ ELIDRISSI A RAMDANI A
Citation
B. Ameduri et al., SYNTHESIS AND PROPERTIES OF AROMATIC TELECHELIC MONODISPERSE DIOLS .1. RADICAL-INITIATED ADDITION OF 10-UNDECEN-1-OL TO NEW AROMATIC ALPHA,OMEGA-DITHIOLS, Macromolecular chemistry and physics, 195(10), 1994, pp. 3425-3443
Citations number
47
Categorie Soggetti
Polymer Sciences
Journal title
Macromolecular chemistry and physics → ACNP
ISSN journal
10221352
Volume
195
Issue
10
Year of publication
1994
Pages
3425 - 3443
Database
ISI
SICI code
1022-1352(1994)195:10<3425:SAPOAT>2.0.ZU;2-D
Abstract
The synthesis of aromatic telechelic monodisperse diols produced from the radical-initiated addition reation of a two-fold excess of 10-unde cen-1-ol and new alpha,omega-dithiols is presented. The dithiols were prepared by esterification of thioglycolic acid with monodisperse tele chelic diols obtained by fractionation of oligo(ethylene terephthalate )s and oligo(tetramethylene terephthalate)s. In all the cases, the lon g-chain alpha,omega-diols were produced selectively and quantitatively . The diols are soluble in most organic solvents, contrary to classica l oligo(ethylene terephthalate)s and oligo(tetramethylene terephthalat e)s.