CHARACTERIZATION OF PERSISTENT ALPHA,OMEGA-DIPHENYL SUBSTITUTED ALLYLCATIONS WITHIN MONODIRECTIONAL ACID ZEOLITES

Authors
CANO ML FORNES V GARCIA H MIRANDA MA PEREZPRIETO J
Citation
Ml. Cano et al., CHARACTERIZATION OF PERSISTENT ALPHA,OMEGA-DIPHENYL SUBSTITUTED ALLYLCATIONS WITHIN MONODIRECTIONAL ACID ZEOLITES, Journal of the Chemical Society, Chemical Communications, (24), 1995, pp. 2477-2478
Citations number
14
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
24
Year of publication
1995
Pages
2477 - 2478
Database
ISI
SICI code
0022-4936(1995):24<2477:COPASA>2.0.ZU;2-E
Abstract
Two alpha,omega-diphenyl substituted allylic cations are generated wit hin ZSM-5 and mordenite as persistent species by adsorption of 1-aceto xy-1,3-diphenylpropane and 1,5-diacetoxy-1,5-diphenylpentane onto the H+-form of these zeolites; the diffuse reflectance spectra of these hi ghly coloured samples (orange or pink) matches the very characteristic absorption spectra of these allyl cations in homogeneous solution; th e non-acidic Na+-form of these zeolites does not have the same effect.