SELECTIVE EPOXIDATION OF ALPHA-ISOPHORONE WITH MESOPOROUS TITANIA-SILICA AEROGELS AND TERT-BUTYL HYDROPEROXIDE

Authors
HUTTER R MALLAT T BAIKER A
Citation
R. Hutter et al., SELECTIVE EPOXIDATION OF ALPHA-ISOPHORONE WITH MESOPOROUS TITANIA-SILICA AEROGELS AND TERT-BUTYL HYDROPEROXIDE, Journal of the Chemical Society, Chemical Communications, (24), 1995, pp. 2487-2488
Citations number
13
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
24
Year of publication
1995
Pages
2487 - 2488
Database
ISI
SICI code
0022-4936(1995):24<2487:SEOAWM>2.0.ZU;2-N
Abstract
Amorphous, mesoporous TiO2-SiO2 mixed oxides, synthesised using a sol- gel process followed by extraction with supercritical CO2, show high s electivities (98%) in the heterogeneous epoxidation of alpha-isophoron e in ethylbenzene at 60 degrees C.