PI-ALLYL PALLADIUM METHODOLOGY FOR SELECTIVE DEPROTECTION OF ALLYLAMINES - PRACTICAL SYNTHESIS OF SECONDARY-AMINES

Authors
LEMAIREAUDOIRE S SAVIGNAC M DUPUIS C GENET JP
Citation
S. Lemaireaudoire et al., PI-ALLYL PALLADIUM METHODOLOGY FOR SELECTIVE DEPROTECTION OF ALLYLAMINES - PRACTICAL SYNTHESIS OF SECONDARY-AMINES, Bulletin de la Societe chimique de France, 132(11), 1995, pp. 1157-1166
Citations number
47
Categorie Soggetti
Chemistry Inorganic & Nuclear",Biology,Chemistry
Journal title
Bulletin de la Societe chimique de France → ACNP
ISSN journal
00378968
Volume
132
Issue
11
Year of publication
1995
Pages
1157 - 1166
Database
ISI
SICI code
0037-8968(1995)132:11<1157:PPMFSD>2.0.ZU;2-Y
Abstract
The palladium-promoted deallylation of allylamines derived from primar y and secondary amines is achieved with high to quantitative yield in the presence of 2-mercaptobenzoic acid as an allyl scavenger. This met hod was used for the sequential cleavage of diallylamines. A. syntheti c application of this procedure is presented in the preparation of sec ondary amines from diallylamines.