THE PROPERTIES AND CRYSTALLIZATION OF LINBO3 IN LITHIUM NIOBOPHOSPHATE GLASSES

Citation
Eb. Dearaujo et al., THE PROPERTIES AND CRYSTALLIZATION OF LINBO3 IN LITHIUM NIOBOPHOSPHATE GLASSES, Journal of physics. Condensed matter, 7(50), 1995, pp. 9723-9730
Citations number
20
Categorie Soggetti
Physics, Condensed Matter
ISSN journal
09538984
Volume
7
Issue
50
Year of publication
1995
Pages
9723 - 9730
Database
ISI
SICI code
0953-8984(1995)7:50<9723:TPACOL>2.0.ZU;2-H
Abstract
Lithium niobophosphate glasses [(xNb(2)O(5) .(0.5 - x)P2O5). 0.5Li(2)O ]:yFe(2)O(3) were studied using infrared spectroscopy and x-ray powder diffraction. The use of the two techniques gives new information abou t the structure of niobium phosphate glasses and glass ceramics. It wa s observed that under heat treatment phosphorus-oxygen groupings of di fferent degrees of complexity, like LiPO3, Li4P2O7 and Li3PO4, were fo rmed. Ferroelectric LiNbO3 crystals were also detected for x = 0.1 nio bium content samples.