ON THE STABILITY OF THE TETRAHEDRAL IN-4V(AG) COMPLEX IN SILVER-HALIDES

Authors
AUSTIN JC SWANSON ML
Citation
Jc. Austin et Ml. Swanson, ON THE STABILITY OF THE TETRAHEDRAL IN-4V(AG) COMPLEX IN SILVER-HALIDES, Journal of physics. Condensed matter, 7(50), 1995, pp. 9747-9754
Citations number
12
Categorie Soggetti
Physics, Condensed Matter
Journal title
Journal of physics. Condensed matter → ACNP
ISSN journal
09538984
Volume
7
Issue
50
Year of publication
1995
Pages
9747 - 9754
Database
ISI
SICI code
0953-8984(1995)7:50<9747:OTSOTT>2.0.ZU;2-S
Abstract
A point defect complex in silver chloride consisting of a trivalent ir on ion in a cube-centre interstitial site, tetrahedrally coordinated w ith four silver vacancies and four halogen ions, was previously detect ed by EPR. In this article we present evidence, obtained by perturbed angular correlation spectroscopy, for a similar defect complex for In3 + in AgCl and AgBr. We present data establishing the existence of this negatively-charged complex, describe its behaviour, and consider why a negatively-charged complex forms.