Yl. Klimontovich, 2 ALTERNATIVE DESCRIPTIONS OF 2ND-ORDER PHASE-TRANSITIONS - LANDAU THEORY AND THE SELF-CONSISTENT APPROACH, Physics letters. A, 210(1-2), 1996, pp. 65-70
Two alternative descriptions of second order phase transitions are con
sidered, Landau theory and the self-consistent approach. The temperatu
re dependence of the heat capacity in these two descriptions is consid
ered. The Landau theory gives only a jump in the heat capacity. It is
not defined by the Gibbs-Boltzmann entropy, which is equal to zero in
the Landau approach, but by the thermal thermodynamical force, The sel
f-consistent approach gives not only this jump, but also the peak in t
he temperature dependence of the heat capacity near the lambda-point.
The latter is defined by the Gibbs-Boltzmann entropy. On the basis of
the S-theorem the relative degree of order of the states above and bel
ow the lambda-point is defined. It is shown that the state below the l
ambda-point is more ordered. Thus, the transition from the more symmet
rical state to the less symmetrical one corresponds to self-organizati
on. The possibility of a kinetic description of second order phase tra
nsitions is considered.