J. Bujdak et al., INVESTIGATION ON THE MECHANISM OF PEPTIDE-CHAIN PROLONGATION ON MONTMORILLONITE, Journal of inorganic biochemistry, 61(1), 1996, pp. 69-78
Experiments with reduced-charge montmorillonites with gradually collap
sed interlayer space prove that peptide formation processes occur main
ly at the edges of the clay mineral. Activation of peptides and amino
acids and the intermediate formation of cyclic anhydrides are found to
be the two dominant processes determining the formation of higher pep
tides on the mineral surface.