A REACTION BETWEEN ALUMINUM-CHLORIDE AND OCTYLDIMETHYLMETHOXYSILANE

Authors
FRIBERG SE ALBAWAB A SJOBLOM J FARRINGTON G NIE WJ
Citation
Se. Friberg et al., A REACTION BETWEEN ALUMINUM-CHLORIDE AND OCTYLDIMETHYLMETHOXYSILANE, Colloids and surfaces. A, Physicochemical and engineering aspects, 105(2-3), 1995, pp. 251-256
Citations number
25
Categorie Soggetti
Chemistry Physical
Journal title
Colloids and surfaces. A, Physicochemical and engineering aspects → ACNP
ISSN journal
09277757
Volume
105
Issue
2-3
Year of publication
1995
Pages
251 - 256
Database
ISI
SICI code
0927-7757(1995)105:2-3<251:ARBAAO>2.0.ZU;2-3
Abstract
The reaction between aluminum chloride and octyldimethylmethoxysilane was investigated at room temperature using NMR and IR spectroscopy com bined with molecular weight determination from freezing point reductio n in benzene. The structure as deduced from the experimental results w as found to be a dimer containing two silicon atoms and two aluminum a toms of which the latter were tetrahedrally coordinated.