Hi. Starnberg et al., VALENCE-BAND PHOTOEMISSION-STUDY OF CS INTERCALATED VSE2, Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 244, 1994, pp. 391-396
We have used photoemission spectroscopy to study the valence band stru
cture of clean and in situ Cs intercalated VSe2. The results show that
the valence band structure of VSe2 is transformed, from initially bei
ng of 3D character, to become essential 2D, as Cs is intercalated. The
changes in the electronic structure are to a large extent understanda
ble as caused by intercalation-induced de-coupling of the VSe2 layers,
and electronic charge transfer from Cs to the host material. Comparis
on with band structure calculations supports this picture. Our finding
s indicate that the Cs/VSe2 system may be of great value in studies of
''reduced dimensionality'' phenomena.