KINETICS AND MECHANISM OF ADDITION OF DIALKYL HYDROGEN PHOSPHITES TO ETHYL BENZOYLFORMATE

Authors
GALKIN VI LOGINOVA IV KONOVALOVA IV BURNAEVA LM CHERKASOV RA
Citation
Vi. Galkin et al., KINETICS AND MECHANISM OF ADDITION OF DIALKYL HYDROGEN PHOSPHITES TO ETHYL BENZOYLFORMATE, Russian journal of applied chemistry, 68(1), 1995, pp. 33-36
Citations number
9
Categorie Soggetti
Chemistry Applied
Journal title
Russian journal of applied chemistry → ACNP
ISSN journal
10704272
Volume
68
Issue
1
Year of publication
1995
Part
1
Pages
33 - 36
Database
ISI
SICI code
1070-4272(1995)68:1<33:KAMOAO>2.0.ZU;2-Y
Abstract
The kinetics and mechanism of addition of dialkyl hydrogen phosphites and their fluorinated analogs to ethyl benzoylformate was studied for the first time by spectrophotometry. The kinetic and activation parame ters of the reactions studied were determined. The inversed reactivity order in the series of dialkyl hydrogen. phosphites was found, the re activities of fluorinated and nonfluorinated dialkyl hydrogen phosphit es being similar. The reactivity of dialkyl hydrogen phosphites in the se reactions is governed by the stereoelectronic effect of substituent s at the phosphorus atom.