METAL GRAPHITE-INTERCALATION COMPOUNDS AS NEW DEHYDROGENATION CATALYSTS

Authors
KLIMKIEWICZ R MORAWSKI AW
Citation
R. Klimkiewicz et Aw. Morawski, METAL GRAPHITE-INTERCALATION COMPOUNDS AS NEW DEHYDROGENATION CATALYSTS, Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 244, 1994, pp. 195-200
Citations number
9
Categorie Soggetti
Crystallography
Journal title
Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals → ACNP
ISSN journal
1058725X
Volume
244
Year of publication
1994
Pages
195 - 200
Database
ISI
SICI code
1058-725X(1994)244:<195:MGCAND>2.0.ZU;2-H
Abstract
The Pb-GICs and K-Bi-GICs as new catalysts for the reaction of oxidati ve dehydrogenation of ethylbenzene have been studied. The reaction occ urred on Pb-graphite with 36.5% selectivity to styrene and 62.5% conve rsion (at 720 degrees C and the feed: ethylbenzene - 3 g/h, water - 15 g/h and air - 6 dm(3)/h). The exploratory results of the application of K-Bi-GICs at 600 degrees C were: selectivity to styrene of 58.4% wi th conversion of 32.2% (ethylbenzene - 2.8 g/h, nitrogen 0.8 dm(3)/h, air - 1.7 dm(3)/h).