APPLICATION OF METAL NITRATE GIC AS NITRATION REAGENT FOR AROMATIC-COMPOUNDS

Authors
STUMPP E EBINAL S
Citation
E. Stumpp et S. Ebinal, APPLICATION OF METAL NITRATE GIC AS NITRATION REAGENT FOR AROMATIC-COMPOUNDS, Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 244, 1994, pp. 207-212
Citations number
10
Categorie Soggetti
Crystallography
Journal title
Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals → ACNP
ISSN journal
1058725X
Volume
244
Year of publication
1994
Pages
207 - 212
Database
ISI
SICI code
1058-725X(1994)244:<207:AOMNGA>2.0.ZU;2-X
Abstract
Hitherto, certain metal nitrates were used as nitrating reagents for a romatic compounds. In this work Zr(NO3)(4)-GIC was used as nitrating r eagent for toluene and phenol in different solvents to give the nitro products in various yields. The reaction products were separated and i dentified by gas chromatography. The GICs were examined by X-ray diffr action and thermogravimetric analysis. Depending on the solvent, the Z r(NO3)(4)-GIC showed a different reactivity towards the aromatic compo unds.