Hp. Lang et al., SCANNING-TUNNELING-MICROSCOPY STUDY OF GRANULAR INTERCALATED FULLERENES, Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 244, 1994, pp. 289-294
We have studied by scanning tunneling microscopy (STM) the surface of
polycrystalline powders of Rb3C60, (KTl1.5)(3)C-60 and (RbTl1.5)(3)C-6
0 (nominal compositions) in a high purity argon environment at 295 K.
Large scale STM images reveal effective grain sizes of some hundred na
nometers. This small grain size strongly reduces the superconductivity
fraction of the diamagnetic shielding. On a molecular scale, the STM
images show ball-shaped features which can be identified with individu
al fullerene molecules in case of Rb3C60(111) and (311) facets, but in
case of (KTl1.5)(3)C-60 and (RbTl1.5)(3)C-60 their apparent diameter
(1.7 nn) is significantly larger, Since AC-susceptibility and X-ray di
ffraction have traced metallic Tl in the (KTl1.5)(3)C-60 and (RbTl1.5)
(3)C-60 samples, we interpret the larger apparent diameter of the ball
-shaped units as a complex of Tl and Rb3C60.