HIGH-TC AND NARROW-BAND IN FULLERENES - THE ANDERSON PARADOX

Authors
Citation
J. Bok et L. Force, HIGH-TC AND NARROW-BAND IN FULLERENES - THE ANDERSON PARADOX, Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 244, 1994, pp. 353-359
Citations number
15
Categorie Soggetti
Crystallography
ISSN journal
1058725X
Volume
244
Year of publication
1994
Pages
353 - 359
Database
ISI
SICI code
1058-725X(1994)244:<353:HANIF->2.0.ZU;2-U
Abstract
High Tc superconductors all have their Fermi level in the middle of a high peak of the density of states (DOS). This explains the value of l ambda, but is not enough to explain their high critical temperature : high DOS is usually associated with a narrow band width, which, as sho wn by Anderson, prevents the renormalization of mu into mu, thus dimi nishing or suppressing Tc. Usually, a sufficient normalisation is stil l possible since the peak is set on a broader band. We calculated the Tc for compounds of the C-60 family: the basis of the peak is not very broad, but the neighbouring bands are very rich in electrons and help the renormalization. The results are in good agreement with experimen ts. The model also explains the variation of Tc with applied pressure and the discrepancy between the measured value of the coherence length and the expected value obtained from the Fermi velocity.