J. Bok et L. Force, HIGH-TC AND NARROW-BAND IN FULLERENES - THE ANDERSON PARADOX, Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 244, 1994, pp. 353-359
High Tc superconductors all have their Fermi level in the middle of a
high peak of the density of states (DOS). This explains the value of l
ambda, but is not enough to explain their high critical temperature :
high DOS is usually associated with a narrow band width, which, as sho
wn by Anderson, prevents the renormalization of mu into mu, thus dimi
nishing or suppressing Tc. Usually, a sufficient normalisation is stil
l possible since the peak is set on a broader band. We calculated the
Tc for compounds of the C-60 family: the basis of the peak is not very
broad, but the neighbouring bands are very rich in electrons and help
the renormalization. The results are in good agreement with experimen
ts. The model also explains the variation of Tc with applied pressure
and the discrepancy between the measured value of the coherence length
and the expected value obtained from the Fermi velocity.