1ST KINETIC MEASUREMENTS ON [H-2(2)]SILYLENE - ABSOLUTE RATE-CONSTANTFOR THE REACTION SID2+H2

Authors
MASON BP FREY HM WALSH R
Citation
Bp. Mason et al., 1ST KINETIC MEASUREMENTS ON [H-2(2)]SILYLENE - ABSOLUTE RATE-CONSTANTFOR THE REACTION SID2+H2, Journal of the Chemical Society. Faraday transactions, 89(24), 1993, pp. 4405-4406
Citations number
10
Categorie Soggetti
Chemistry Physical","Physics, Atomic, Molecular & Chemical
Journal title
Journal of the Chemical Society. Faraday transactions → ACNP
ISSN journal
09565000
Volume
89
Issue
24
Year of publication
1993
Pages
4405 - 4406
Database
ISI
SICI code
0956-5000(1993)89:24<4405:1KMO[->2.0.ZU;2-S
Abstract
SiD2, generated via the laser flash photolysis of phenyl [H-2(3)]Silan e, has been detected via a ro-vibrational transition in its A(1B1) <-- X(1A1) absorption band. It has been monitored for the first time in t ime-resolved studies to give an absolute rate constant of (3.8 +/- 0.2 ) X 10(-12) cm3 molecule-1 s-1 for the reaction SiD2 + H2. Product SiH 2 from this reaction was also observed.