DETERMINATION OF THE STEREOCHEMISTRY OF 4 SPIRODIASTEREOISOMERS BY ONE-DIMENSIONAL AND 2-DIMENSIONAL NOE STUDIES

Authors
MORENO A DIAZORTIZ A DIEZBARRA E DELAHOZ A LANGA F PRIETO P CLARIDGE TDW
Citation
A. Moreno et al., DETERMINATION OF THE STEREOCHEMISTRY OF 4 SPIRODIASTEREOISOMERS BY ONE-DIMENSIONAL AND 2-DIMENSIONAL NOE STUDIES, Magnetic resonance in chemistry, 34(1), 1996, pp. 52-58
Citations number
7
Categorie Soggetti
Spectroscopy,Chemistry
Journal title
Magnetic resonance in chemistry → ACNP
ISSN journal
07491581
Volume
34
Issue
1
Year of publication
1996
Pages
52 - 58
Database
ISI
SICI code
0749-1581(1996)34:1<52:DOTSO4>2.0.ZU;2-R
Abstract
The stereochemistries of four cycloadducts obtained by 1,3-dipolar rea ctions were investigated with one- and two-dimensional NMR techniques, Analysis of a series of homonuclear NOE difference spectra and COSY a nd NOESY spectra recorded in a variety of solvents and at various temp eratures allowed the determination of the full stereochemistry of each adduct.