NONISOTHERMAL DECOMPOSITION KINETICS OF TRONA

Citation
A. Ekmekyapar et al., NONISOTHERMAL DECOMPOSITION KINETICS OF TRONA, Industrial & engineering chemistry research, 35(1), 1996, pp. 258-262
Citations number
12
Categorie Soggetti
Engineering, Chemical
ISSN journal
08885885
Volume
35
Issue
1
Year of publication
1996
Pages
258 - 262
Database
ISI
SICI code
0888-5885(1996)35:1<258:NDKOT>2.0.ZU;2-M
Abstract
In the present work, experiments on the nonisothermal decomposition of trona in thermogravimetric analysis (TGA) and differential scanning c alorimetry (DSC) devices were carried out, and kinetic analysis of the process was performed by employing four different approaches. It was determined that the process fits a first-order reaction kinetic model and that the value of the activation energy changes, to some degree, d epending upon the method used in the analysis, with a maximum deviatio n of 8.9% from the average value. The activation energy was found to b e approximately 112 kJ mol(-1), which is in good agreement with the da ta from similar studies in the literature.