NATURAL-ABUNDANCE O-17 NMR INVESTIGATION OF 4-SUBSTITUTED N-METHYLBENZAMIDES AND N,N-DIMETHYLBENZAMIDES - DIMINUTION OF SUBSTITUENT EFFECTSBY TORSION-ANGLE TWIST

Authors
SPYCHALA J BOYKIN DW
Citation
J. Spychala et Dw. Boykin, NATURAL-ABUNDANCE O-17 NMR INVESTIGATION OF 4-SUBSTITUTED N-METHYLBENZAMIDES AND N,N-DIMETHYLBENZAMIDES - DIMINUTION OF SUBSTITUENT EFFECTSBY TORSION-ANGLE TWIST, Journal of chemical research. Synopses, (10), 1993, pp. 426-427
Citations number
31
Categorie Soggetti
Chemistry
Journal title
Journal of chemical research. Synopses → ACNP
ISSN journal
03082342
Issue
10
Year of publication
1993
Pages
426 - 427
Database
ISI
SICI code
0308-2342(1993):10<426:NONIO4>2.0.ZU;2-N
Abstract
Natural abundance O-17 NMR spectroscopic data for eleven N-methylbenza mides (1a-k) and eleven N,N-dimethylbenzamides (2a-k) obtained at 75-d egrees-C in acetonitrile solution are correlated with Hammett sigma+ c onstants; rho+ values for the two systems are 6.7 and 2.2, respectivel y,